You didn't tell me that you had eliminated the possibility that it is a bad slot, i.e. two sticks will run in any two slots. Or you could have placed a stick in each of the 3 slots one at a time and booted.
ASUS P8Z68-V Pro , Intel i7 2600K @4.7Ghz using 1.38V
-- GSkill DDR3 2133 (2*2Gb) 9-10-10-28
-- Iwaki MD-20RLZT -> EK Sup. Univ. -> Chiller -> Resev
-- EVGA GTX570, SB Audigy2ZS + Klipsch Promedia 4.1
-- 120G Intel 510, 120G RST RAID 0, Areca RAID 5, 4 80G SATAII HDDs
-- PC P&C Silencer 750 QUAD in Lian-Li PC-V1200
-- Win7 64-bit, Ubuntu 64-bit
ASUS Rampage II Extreme @180Mhz, Intel i7 920 D0 @3.6Ghz using 1.3V, Thermalright 120
-- G.Skill DDR3 1600 (3*2Gb) 8-8-8-21, Win7 64-bit
-- Lian-Li PC-V1200